LOS ANGELES (WATE) – One of Hollywood’s highest profile marriages is over.

Angelina Jolie Pitt has filed for divorce from Brad Pitt, her husband of almost two years, an attorney for Jolie Pitt told The Associated Press. Jolie cited “irreconcilable differences and asked for physical custody of the couple’s six children, according to TMZ

Jolie and Pitt became a couple after starring in Mr. and Mrs. Smith. in 2004. They were secretly married in France in 2014. The Jolie-Pitt kids— Maddox, Pax, Zahara, Shiloh, and twins Knox and Viviennne—participated in their parents’ wedding.

This was the second marriage for Pitt, who was previously married to actress Jennifer Aniston, and the third for Jolie Pitt, who was married to Jonny Lee Miller and Billy Bob Thornton.